Cytosine monohydrate
WebSingle crystals of cytosine monohydrate were irradiated with ..gamma.. rays at 77 K, and the electron spin resonance (ESR) spectra were recorded while gradually increasing the temperature. The analysis of the decrease in line intensity shows that the disappearance of cation and anion radicals is due predominantly to their mutual recombination. WebNov 8, 2024 · Monohydrate and anhydrate crystalline forms of the DNA nucleobase cytosine interconvert via a topotactic solid-state mechanism where water functions as a molecular switch. The solid-state dehydration …
Cytosine monohydrate
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WebJun 1, 2016 · Cytosine is one of the pyrimidine derivatives which consists of heterocyclic compound along with aromatic amine and keto groups [2], [3]. Cytosine plays an important role in DNA/RNA base pairing, through several hydrogen-bonding patterns and controls the essential features of life as it is involved in genetic codon of 17 amino acids [4]. WebThe Cambridge Structural Database (CSD)26 contains each two distinct anhydrate …
WebThe radicals were induced by X-irradiating single crystals of cytosine monohydrate, substitutionally doped with 2-thiocytosine. X-irradiation and measurements were carried out at about 15 K. The electron-loss radicals were found to be associated with the thiocytosine molecules in a proportion much above the thiocytosine/cytosine ratio in the ... WebDec 1, 1995 · Assuming an average theoretical value of kappa H = 1.24, the molecular dipole moments calculated from the monopole and dipole pseudoatom population parameters are 17 (4) and 8.2 (15) Debye for cytidine nucleoside and cytosine in the monohydrate, respectively. Systems of atomic point charges are presented for cytidine, …
Webcytosine, a nitrogenous base derived from pyrimidine that occurs in nucleic acids, the heredity-controlling components of all living cells, and in some coenzymes, substances that act in conjunction with enzymes in chemical reactions in the body. Cytosine is one of … nucleic acid, naturally occurring chemical compound that is capable of being … RNA, abbreviation of ribonucleic acid, complex compound of high molecular … WebMar 10, 2010 · The enantioselective formation of chiral crystal of achiral nucleobase cytosine was achieved mediated by the crystal direction selective dehydration of crystal water in the achiral crystal of cytosine monohydrate (P2(1)/c). Heat transfer from the enantiotopic face of the single crystal of cytosine m …
WebCytosine monohydrate Oxidation of cytosine produces a radical with sites of unpaired …
WebFeb 1, 2014 · The crystal structure of cytosine (Barker & Marsh, 1964) and cytosine monohydrate (Jeffrey & Kinoshita, 1963) were determined many years ago. Many inorganic cytosinium salts have been synthesized, including the hydrochloride (Mandel, 1977) and the dihydrogenmonophosphate (Bagieu-Beucher, 1990) salts. raw dried sea mossWebCytosine definition, a pyrimidine base, C4H5N3O, that is one of the fundamental … simple cow factsWebIn neutron diffraction experiments on crystalline cytosine monohydrate, 3 the HNCN out-of-plane angle was determined to be 3.4°, and a slight puckering of the ring was observed. Including hydrogen bonding moieties in the optimization calculations (four water molecules surrounding the N1 radical of cytosine) lowered the amino group puckering to ... raw duck headWebCytosine and cytosine monohydrate are representative biomolecules for investigating the effect of hydrogen bonds in deoxyribonucleic acid. To better understand intermolecular interactions, such as hydrogen bonds, between nucleobases it is necessary to identify the low-frequency vibrational modes associated with intermolecular interactions and … raw drive won\u0027t formatWebCytosinium 4-nitrobenzoate cytosine monohydrate C15H17N7O7 CID 139060525 - … rawdy heckenlivelyWebThe total free radical yield has been measured for crystals of five pyrimidine derivatives: thymine (T), 1-methylthymine (1MeT), 1-methyluracil (1MeU), 1-methylcytosine (1MeC) and cytosine monohydrate (C:HOH). Q-band EPR measurements were made on samples X-irradiated between 4 and 12 K. The G values … raw dry food for dogsWebAbstract Single crystals of anhydrous thymine (Ta) and cytosine monohydrate (Cm) were irradiated at room temperature using X rays, 20 MeV protons and 35 MeV alpha particles, and the relative distributions of the various radiation-induced stable radicals in the crystals were investigated. raw drives won\\u0027t show up in disk management